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GSH has a free electron it can donate to reactive oxygen species, such as free radicals, to neutralize them, thus preventing them from damaging cells

10.1016/j.phymed.2020.153211 96 YangY.ChenJ.GaoQ.ShanX.WangJ.LvZ

In the skin, ROS are generated continuously, however, they can be eliminated by a variety of antioxidant substrates (Richelle et al., 2006)

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While under hypoxia both NADP and glutathione showed oxidation with matching dynamics, re-oxygenation caused pronounced further oxidation of glutathione while NADP recovered to a more reduced state